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The
coupling
in QCD depends on the
renormalization point
used to define it. Although the complete rate for any process must be independent of
, it may be that a suitable choice of
will allow many of the higher order terms in the perturbation series for the rate to be absorbed into the coupling
. In this paper I shall consider primarily processes which depend on only one kinematic invariant. For a particular value of
, all terms in these processes up to
may be absorbed into an effective coupling
, but in higher orders, there exist terms which cannot be accounted for in this way. The choice of
which causes the most terms in the perturbation series to be absorbed into the effective coupling is proportional to the value of the kinematic invariant. However, the constant of proportionality, and hence the magnitude of the effective coupling for a particular value of the invariant, depends sensitively on the details of the process considered. I shall discuss at length processes of the form (
is a gluon)

and then give a briefer discussion of several other processes. The non-Abelian nature of QCD introduces inessential complications into the discussion, and so I shall ignore it throughout. With this simplification (which is equivalent to considering QED rather than QCD), the square of the amplitude for (1) to order
is given by the classes of diagrams in Fig. 1. I assume that there can be no gluon corrections to the
or
lines (the gluon may be considered to carry conserved quantum numbers possessed by
but not by
). I take the effective ABG vertex to be of the form (1)

where
is the invariant mass of the gluon, and
.
If the quark mass (
) were taken to be non-zero, than the gluon propagator could be renormalized on shell, so that the diagrams giving corrections to single real gluon emission would not contribute. In that case the total rate for (1) is given by (removing a trivial phase space factor for the diagram
)

where
is the reduced gluon vacuum polarization operator, including improper vacuum polarization diagrams such as
. To lowest order, as usual

To order
, therefore, taking
, the diagrams
and
give

for
. This rate clearly diverges as
. For
, however, one must perform renormalization at
. In that case, the diagram
gives a contribution (a
pair with zero invariant mass cannot be distinguished from a real gluon)

if
. Adding (5) and (6) the complete rate for the process (1) to
in the limit
becomes

where
if
.
In eq. (7) I have displayed the fact that the couplings depend on the renormalization point
; they obey the renormalization group equation (RGE)
. Of course, the renormalizability of QCD guarantees that at each order in
the rate
cannot depend on
, so that
. Nevertheless, by a suitable choice of
the expression in braces in (7) may be absorbed into the effective coupling
. Keeping only the
term in
one has (e.g., [1])

where
is a renormalization group invariant mass (2) used to set the scale of the effective coupling. If the constant
in eq. (7) were zero, then by choosing
the rate
could be rewritten (at least to
) as
. This expression for the rate could be written in terms of
again by using the first form in eq. (8), giving

which agrees with (7) (with
) to
, but contains further higher-order terms. The form (9) is a conventional `renormalization group improved' estimate for
.
For any physical value of
, however,
is non-zero. Hence a re-expansion of
in terms of
will not give the correct form (7); the `constant' term proportional to
will be missing. A simple trick may, however, be used to remedy this deficiency. Instead of choosing
, take
and arrange
so that the term in brackets in eq. (7) vanishes (i.e.,
). In that case, the `renormalization group improved' estimate
will agree with the full perturbation theory result, at least to order
. Instead of taking
, one could take
, but replace the
in the eq. (8) for
by an effective 
At
(in the `unimproved' perturbation series) the coupling is fixed. Higher-order terms may be interpreted as inducing a dependence of the coupling on
. Since this dependence is governed by the RGE, some of the higher-order terms in the perturbation series for
are determined. In particular, the coefficient of the
in eq. (7) is determined. However, the constant
is not, and depends on the value of
which characterizes the ABG vertex. Hence the choice of
in
which gives the correct non-logarithmic term at
depends on
. Alternatively, the effective value of
if
is sensitive to constant terms at
and hence to
. (3) Table 1 gives the values of
and
for various
. (4) Note the large difference of
from one in all cases, and the strong dependence of
on
. Let us temporarily ignore
and higher terms. Then eq. (7) gives the exact rate for the process (1) which could, in principle, be measured experimentally. The experimental measurement could be used to determine the effective QCD coupling. Of course, the measured size of the coupling could be fit to the formula of eq. (8) and an effective value of
deduced. However, because of the presence of constant terms, this effective
will differ from the true
. It is clear from Table 1 that the difference is rather large, and depends considerably on
. To
the rates for all processes which depend on only one invariant will have the form (7), so that the same phenomena will occur. For example, if the measured cross-section for
is fit to the naive QCD prediction
then the effective
deduced will not necessarily be even close to the true value of
. To obtain a better estimate of the true
from the experimental
, one must compute the constant
in (
is the effective number of quark flavors)

Agreement between values of
deduced from experimental measurements of various processes without making at least this correction is clearly not a direct prediction of QCD. Rather it will occur only if (unlike the case of changing
) the constant
does not differ significantly between the processes considered.

resulting from the inclusion of constant terms
at
for various forms of
transition.
I return now to process (1), and discuss the
contributions to its rate. Examples of the relevant classes of diagrams are given in Fig. 1. The iterated (`improper')
vacuum polarization diagrams (
,
) contribute

to
, while the diagrams involving true
vacuum polarization contribute

The coefficient of the
in (11) corresponds to the
term in the expansion of the effective coupling (8) deduced from the
term in
, while the coefficient of the log in (12) corresponds to the
term [2] in
. (5) The coefficient of the log in (11) depends on the constant
at
. If the effective coupling is computed from
keeping up to
in 
and then this coupling, evaluated at
, is used to estimate the rate for (1) using
, then not only will the constant term at
be missed, but also a part of the
at
. Of course, the same choice of
which accounts for the constant at
will also account for the
at
. However, the constant terms
at
remain unaccounted for even when
. If
, then
and the full form of
to
is [3]

I showed above that to
, a suitable choice of
allows the rate for (1) to be written simply as
. The value of
is chosen so that the expansion of the `renormalization group improved' effective coupling
(obtained from
) in terms of
agrees with the explicit perturbation theory result (7) for
to
. However, if
is expanded to
there is no longer a choice of
such that
to
. This is because the equation to determine
both depends on
and in general has no real roots (if only the
terms are considered, the quadratic equation for
has no real roots). Hence the trick of changing the renormalization point or of modifying the effective
to account for the constant terms at
cannot be used at
, and the naive prescription for including higher-order effects by replacing the
encountered in a lowest-order calculation by
has failed. Nevertheless, whereas the effective value of
is very sensitive to the
terms in
, it is not particularly affected by the
terms, at least for
sufficiently small that perturbation theory should be reliable. The change in
due to
terms is given very approximately by
, where
is the
constant term in
. For reasonable values of
, the change is less than about 25%.
I shall now discuss briefly the effective coupling in quark-quark scattering through one-gluon exchange, again ignoring non-Abelian effects. The amplitude for this process is proportional to the real part of the improper gluon vacuum polarization, which is related to
by a once-subtracted dispersion relation (assuming
, and taking
):

This is very closely related to the formula (3) for
when
. In the limit
,
to
, and in fact, for all terms in
of the form
the principal part of the
integral in (14) vanishes as
, so that result holds. At
,
contains a term
. In that case the results for
and
differ by
. The result for the
scattering amplitude (which may be deduced directly from the calculation of Källén and Sabry [4] (6) ) is

where
is the invariant mass transferred along the gluon. It is clear that the conclusions reached above for the process (1) also apply here.
I now give several further examples of the phenomena discussed above. The first is the anomalous magnetic moment
of a charged lepton
in QED. Using the lowest-order result,
, the RGE gives
[6]

Explicit perturbation theory calculations show that (e.g., [7])

If one makes the conventional choice
then
the logarithms in (16) become
. If
, they therefore do not contribute. However, if
, they will contribute and generate a large part of the difference between
and
. In practice there are also terms arising from the presence of new diagrams in the
case, containing both
and
loops, and in addition terms of order
, which are not amenable to a RGE analysis. Nevertheless the coefficients of the logarithmic terms at
are determined by the RGE [6]. From eq. (16) one may deduce the value of
which would allow the complete
term to be absorbed into the effective coupling. The result is
.
The second example is the decay of positronium. The rate for the decay of the
state is given by [8]

yielding
. For the
state, [9]

so that
. It is clear from this example that the effective value of
deduced from
decays may differ considerably from the true
. The complete cross-section (averaged over the initial spins) for
annihilation in the nonrelativistic limit is of the form (17), but with [10]
, corresponding to
.
Finally it should be pointed out that in QED there exist low-energy theorems which show that the cross-sections for certain processes (for example,
[11]) in the nonrelativistic limit are proportional simply to
, and contain no constant terms. In QCD, however, analogous low-energy theorems are rendered useless by the strong coupling of the theory in the low-energy domain.
In this paper I have considered only processes which depend on one kinematic invariant. For processes which involve two invariants (e.g., the total cross-section for deep inelastic lepton-hadron scattering) similar results should hold, but the value of
which causes all
terms to be absorbed into the effective coupling will then consist of a dimensionless combination of the invariants.
I am grateful to several people for discussions, especially G. C. Fox, H. D. Politzer and A. E. Terrano.