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It is expected [4] that the effects of operators occurring in the operator product expansion with twists greater than two become very important for
, corresponding to
(terms of higher order in
also diverge in the limit
at fixed
, but this is only significant at much larger values of
). Starting distributions need only be rejected, therefore, if they lead to negative distributions for
(
). Nevertheless, as explained in sect. 1, it is interesting to consider the limit
, where we find

where

For
, the factor
is negative. The distributions therefore become negative unless the first terms in eq. (10a) dominate as
. Making the assumption of eq. (2) for the behaviour of the starting distributions as
and
behave like
and
, respectively, for large
. Eq. (3) is then the condition that
and
remain positive for
. If the inequalities of eq. (3) are satisfied,
remains positive for all
but
still becomes negative for
sufficiently small. For
this occurs at

As stated in sect. 1, it is clear that distributions for
generated from any starting distributions must obey eq. (3). When
at fixed
,

so that eq. (10a) shows that
: but in general this will only become true at extremely high
when the structure functions will all be infinitesimal for
close to one. To make more useful statements about the form of the structure functions for
, we must assume a particular form for the starting distributions. If, for example, following ref. [5], we take
for
, then, ignoring
terms, eqs. (10) and (4) give
for
.
Next we consider the
moments. The energy-momentum sum rule implies
, so that for the singlet structure functions

Hence The value of Figs. 1 and 2 show that the observed values of
will inevitably become negative as
, unless
, in which case
will become negative. In fig. 1 we have plotted the value of
below which
or
becomes negative (which we call
as a function of
) for
and
(the results are very insensitive to the number of flavours). The very reasonable demand that
requires
)
, (experimentally
)
and if
(by which point higher-twist operators should be becoming significant for
),
.

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[ Figure 2 ] The value
of
below which the predicted total
momentum carried by one flavour of antiquark
becomes negative, as a
function of the momentum it carried at
for various starting gluon
momenta,
) (
and
).
at which
becomes negative is easily calculated from eq. (4) as a function of
and
using the fact that
and
(which has already been used in deriving eq. (11)). The results are shown in fig. 2 for
and
(they are insensitive to
). The reasonable demand that
gives
)
for
and
implies
. Neutrino data suggest that
not greatly in excess of this bound. For strange quarks the bound probably fails with
but larger
is needed for it to be credible in this case. However, our bounds show that the distributions of new flavours must be non-zero in regions of
where the application of asymptotic freedom formulae to them is at all reasonable.
and
are obtained if
and
vanish at
. This was originally pointed out in ref [5].